Structural modifications of LixV2O5 in a composite cathode (0≤x < 2) investigated by Raman microspectrometry
Article first published online: 27 JUN 2011
Copyright © 2011 John Wiley & Sons, Ltd.
Journal of Raman Spectroscopy
Volume 43, Issue 1, pages 153–160, January 2012
How to Cite
Baddour-Hadjean, R., Marzouk, A. and Pereira-Ramos, J. P. (2012), Structural modifications of LixV2O5 in a composite cathode (0≤x < 2) investigated by Raman microspectrometry. J. Raman Spectrosc., 43: 153–160. doi: 10.1002/jrs.2984
- Issue published online: 27 JAN 2012
- Article first published online: 27 JUN 2011
- Manuscript Accepted: 11 APR 2011
- Manuscript Received: 23 FEB 2011
- LixV2O5, composite electrode;
- Raman microspectrometry;
- lithium battery;
- lithium intercalation compound
The structural behaviour of the LixV2O5 active material in a composite electrode is determined upon lithium insertion/extraction in the 4–2.15 V potential range (0≤x < 2) using Raman microspectrometry. For the first time, a detailed description of phase transitions occurring in the V2O5 composite electrode is provided by Raman spectroscopy, on the basis of a complete assignment of the spectra. This approach has been successful because of the knowledge of the Raman fingerprints of the chemically lithiated compounds, combined with a rigorous and systematic deconvolution of the Raman spectra obtained for the electrochemically lithiated materials. The successive emergence of α, ε, δ and γ phases is clearly established, as well as the α/ε, ε/δ and δ/γ biphasic regions corresponding to the 3.4, 3.2 and 2.3 V potential plateaus, respectively. This study shows that Raman spectroscopy constitutes a sensitive and relevant tool to explore the emergence of the various phases governing the electrochemical properties of cathode materials for lithium batteries. Copyright © 2011 John Wiley & Sons, Ltd.