This article is part of the Journal of Raman Spectroscopy special issue entitled “Raman spectroscopy in art and archaeology” edited by Juan Manuel Madariaga and Danilo Bersani.
Raman spectroscopy analysis of Palaeolithic industry from Guadalteba terrace river, Campillos (Guadalteba county, Southern of Iberian Peninsula)†
Article first published online: 26 JUL 2012
Copyright © 2012 John Wiley & Sons, Ltd.
Journal of Raman Spectroscopy
Special Issue: Raman spectroscopy in art and archaeology
Volume 43, Issue 11, pages 1651–1657, November 2012
How to Cite
Hernández, V., Jorge-Villar, S., Capel Ferrón, C., Medianero, F. J., Ramos, J., Weniger, G.-C., Domínguez-Bella, S., Linstaedter, J., Cantalejo, P., Espejo, M. and Durán Valsero, J. J. (2012), Raman spectroscopy analysis of Palaeolithic industry from Guadalteba terrace river, Campillos (Guadalteba county, Southern of Iberian Peninsula). J. Raman Spectrosc., 43: 1651–1657. doi: 10.1002/jrs.4104
- Issue published online: 21 NOV 2012
- Article first published online: 26 JUL 2012
- Manuscript Accepted: 31 MAR 2012
- Manuscript Revised: 22 MAR 2012
- Manuscript Received: 14 NOV 2011
- Raman microscopy;
- portable Raman spectrometer;
- lithic tools
A representative set of eight lithic tools suitably selected among the very rich Palaeolithic industry collected over the past years in different archaeological sites of the Guadalteba County (Málaga, Spain) has been nondestructively investigated by means of Raman spectroscopy using both portable and benchtop Raman spectrometers. This article reports on the first archaeometric Raman analysis of these archaeological samples with the scope of checking if these readily available, nondestructive, fast and cheap vibrational spectroscopic techniques, which in addition do not require a preliminary sample preparation, could provide any meaningful information for characterizing the mineral composition of chert artefacts and ultimately some specific arguments about their assignment to distinctive groups of raw materials of a particular provenance. On the basis of the vibrational data, it was confirmed that α-quartz was the raw material in all the cases, although a small amount of moganite was also evidenced as a distinctive fingerprint in these chert samples. On the other hand, crusts were mainly made of calcite in all the cases, sometimes accompanied by other minerals such as barite or anatase. This first Raman spectroscopic study on chert and sandstone artefacts from the Guadalteba county reveals that there are good premises for a further and more thorough archaeometric investigation of these lithic tools based on sets of Raman measurements (Raman mapping) on each specimen rather than on single-point Raman experiments such as in the present case, given the wide macroscopic heterogeneity of this kind of samples (colour, grain size, transparency, etc.). The Raman-mapping archaeometric analyses of bulks and crusts would be also complemented with X-ray diffraction and X-ray fluorescence data. Copyright © 2012 John Wiley & Sons, Ltd.