High-resolution stimulated Raman spectroscopy and analysis of the ν1, 2ν1–ν1, ν2, 2ν2, and 3ν2–ν2 bands of CF4
Version of Record online: 3 FEB 2013
Copyright © 2013 John Wiley & Sons, Ltd.
Journal of Raman Spectroscopy
Volume 44, Issue 5, pages 731–738, May 2013
How to Cite
Boudon, V., Bermejo, D. and Martínez, R. Z. (2013), High-resolution stimulated Raman spectroscopy and analysis of the ν1, 2ν1–ν1, ν2, 2ν2, and 3ν2–ν2 bands of CF4. J. Raman Spectrosc., 44: 731–738. doi: 10.1002/jrs.4248
- Issue online: 10 MAY 2013
- Version of Record online: 3 FEB 2013
- Ministry of Science and Innovation. Grant Number: FIS2009-08069
- carbon tetrafluoride;
- high-resolution stimulated Raman spectroscopy;
- tensorial formalism;
- bond length
The spectra of the ν1, 2ν1–ν1, ν2, 2ν2, and 3ν2–ν2 bands of CF4 were obtained with a quasi-continuous wave stimulated Raman spectrometer. These five bands were studied at a temperature of 135 and 300 K (for the hot bands). The spectrum of ν1 was obtained at a sample pressure of 2 mbar. For the spectra of the other regions, which are much weaker, higher pressures were used. The analysis has been performed thanks to the xtds and spview softwares developed in Dijon for such highly symmetric molecules. Combining the present results with a previous infrared study, we could determine a very accurate value for the C–F equilibrium bond length, i.e. re = 1.31588(6) Å. Copyright © 2013 John Wiley & Sons, Ltd.