Technical investigation of 15th and 19th century Chinese paper currencies: Fiber use and pigment identification
Article first published online: 18 APR 2013
Copyright © 2013 John Wiley & Sons, Ltd.
Journal of Raman Spectroscopy
Volume 44, Issue 6, pages 892–898, June 2013
How to Cite
Shi, J.-l. and Li, T. (2013), Technical investigation of 15th and 19th century Chinese paper currencies: Fiber use and pigment identification. J. Raman Spectrosc., 44: 892–898. doi: 10.1002/jrs.4297
- Issue published online: 5 JUN 2013
- Article first published online: 18 APR 2013
- Manuscript Accepted: 28 FEB 2013
- Manuscript Revised: 7 FEB 2013
- Manuscript Received: 8 OCT 2012
- Da ming bao chao;
- Da qing bao chao;
- Hu bu guan piao;
- Herzberg staining;
- Raman spectroscopy
Herzberg staining, a quick and convenient tool for distinguishing non-wood fibers from wood pulp, and Raman spectroscopy were employed to investigate three paper currencies issued under the reign of the Chinese Ming and Qing Emperors between 15th and 19th centuries - da ming bao chao (AMS C-14 Date: 1410-1435 AD, ±1σ) from the Early Ming Dynasty (1405–1433 AD) and da qing bao chao (1859 AD) and hu bu guan piao (1854–1858 AD) from the Late Qing Dynasty (1840–1911 AD). Fiber staining and microscopic examination revealed a predominance of bast fiber from probably mulberry trees and very few cotton fibers (supposed to be environment contamination) in da ming bao chao; fibers in da qing bao chao and hu bu guan piao turned out to be quite pure, which are also bast fibers but very likely came from ramie and paper mulberry trees, respectively.
Raman analysis of red, blue, and black pigments on the investigated paper currencies showed that: (1) The reddish seal on da ming bao chao is not a vermilion (HgS) paste, as it is traditionally assumed, but instead a red lead (or minium, Pb3O4) one. The red pigments on both da qing bao chao and hu bu guan piao are vermilion (HgS). (2) Prussian blue (Fe7(CN)18⋅14-16H2O), a Western pigment, was identified as blue on both da qing bao chao and hu bu guan piao. (3) The black pigment on all these three paper currencies is amorphous carbon from soot. (4) Raman analysis of evenly distributed white pigment particles among the fibers in da qing bao chao confirmed the use of calcium carbonate (CaCO3) as coating pigment or fillers. Both microscopic examination of stained fibers and Raman analysis allowed, for the first time, the understanding of fiber and pigment use in producing ancient Chinese paper currencies. Copyright © 2013 John Wiley & Sons, Ltd.