This article is from the ECONOS part of the joint special issue on the European Conference on Nonlinear Optical Spectroscopy (ECONOS 2012) with Guest Editors Johannes Kiefer and Peter Radi and the II Italian Conference of the National Group of Raman Spectroscopy and Non-Linear Effects (GISR 2012) with Guest Editor Maria Grazia Giorgini.
Effect of vibration–rotation coupling on simultaneous extraction of temperature and species concentration from vibrational CARS spectra of hot gases†
Article first published online: 7 AUG 2013
Copyright © 2013 John Wiley & Sons, Ltd.
Journal of Raman Spectroscopy
Special Issue: Joint special issue on the European Conference on Nonlinear Optical Spectroscopy (ECONOS 2012) and the II Italian Conference of the National Group of Raman Spectroscopy and Non-Linear Effects (GISR 2012)
Volume 44, Issue 10, pages 1326–1329, October 2013
How to Cite
Marrocco, M. (2013), Effect of vibration–rotation coupling on simultaneous extraction of temperature and species concentration from vibrational CARS spectra of hot gases. J. Raman Spectrosc., 44: 1326–1329. doi: 10.1002/jrs.4357
- Issue published online: 22 OCT 2013
- Article first published online: 7 AUG 2013
- Manuscript Accepted: 28 JUN 2013
- Manuscript Revised: 4 APR 2013
- Manuscript Received: 12 MAR 2013
- coherent anti-Stokes Raman scattering;
- laser spectroscopy;
- spectroscopic techniques
The coupling between vibration and rotation in light molecules changes the strength of the Raman response. From this standpoint, we consider high-temperature molecular spectra obtained by means of coherent anti-Stokes Raman scattering (CARS), whose spectral intensity is useful to extract thermometric information and species concentrations for applications in combustion science. In this context and unlike other studies on the subject that are exclusively focused on thermometry, the novelty of the current work lies in the determination of the mutual relationship among the free variables adopted in the analysis of CARS spectra when these do not include the effect of the vibration–rotation coupling. The relationship emerges from the comparison to a reference made of calculated vibrational spectra of nitrogen and oxygen subject to the coupling. These spectra are then fitted by means of spectra developed under the ordinary rigid-rotor approximation that is usually adopted in any fitting procedure for such molecules. The results show that small changes of the fitted temperature correspond to larger deviations for the determination of concentrations and non-resonant background. Copyright © 2013 John Wiley & Sons, Ltd.