Parts of this work were initially presented at the Fall Eastern States Section Technical Meeting of the Combustion Institute, Pennsylvania State University, University Park, PA, October 26–29, 2003.
An updated comprehensive kinetic model of hydrogen combustion†
Article first published online: 4 AUG 2004
Copyright © 2004 Wiley Periodicals, Inc.
International Journal of Chemical Kinetics
Volume 36, Issue 10, pages 566–575, October 2004
How to Cite
Li, J., Zhao, Z., Kazakov, A. and Dryer, F. L. (2004), An updated comprehensive kinetic model of hydrogen combustion. Int. J. Chem. Kinet., 36: 566–575. doi: 10.1002/kin.20026
- Issue published online: 4 AUG 2004
- Article first published online: 4 AUG 2004
- Manuscript Accepted: 11 MAY 2004
- Manuscript Revised: 2 MAY 2004
- Manuscript Received: 8 JAN 2004
- Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, Office of Science, U.S. Department of Energy. Grant Number: DE-FG02-86ER13503
A comprehensively tested H2/O2 chemical kinetic mechanism based on the work of Mueller et al. 1 and recently published kinetic and thermodynamic information is presented. The revised mechanism is validated against a wide range of experimental conditions, including those found in shock tubes, flow reactors, and laminar premixed flame. Excellent agreement of the model predictions with the experimental observations demonstrates that the mechanism is comprehensive and has good predictive capabilities for different experimental systems, including new results published subsequent to the work of Mueller et al. 1, particularly high-pressure laminar flame speed and shock tube ignition results. The reaction H + OH + M is found to be primarily significant only to laminar flame speed propagation predictions at high pressure. All experimental hydrogen flame speed observations can be adequately fit using any of the several transport coefficient estimates presently available in the literature for the hydrogen/oxygen system simply by adjusting the rate parameters for this reaction within their present uncertainties. © 2004 Wiley Periodicals, Inc. Int J Chem Kinet 36: 566–575, 2004