Part 1: cf.1.
Absorption of low molecular weight compounds in aqueous dispersions of polymer-oligomer particles, 2. A two step swelling process of polymer particles giving an enormous increase in absorption capacity†
Version of Record online: 12 MAR 2003
© 1979 Hüthig & Wepf Verlag, Basel
Die Makromolekulare Chemie
Volume 180, Issue 3, pages 737–744, 1 March 1979
How to Cite
Ugelstad, J., Kaggerud, K. H., Hansen, F. K. and Berge, A. (1979), Absorption of low molecular weight compounds in aqueous dispersions of polymer-oligomer particles, 2. A two step swelling process of polymer particles giving an enormous increase in absorption capacity. Makromol. Chem., 180: 737–744. doi: 10.1002/macp.1979.021800317
- Issue online: 12 MAR 2003
- Version of Record online: 12 MAR 2003
- Manuscript Received: 28 FEB 1978
A novel method for preparation of stable emulsions of slightly water soluble compounds is described. The method implies that the slightly water soluble compound diffuses through water and becomes absorbed into polymer particles which in a previous step have been brought to absorb a water insoluble, relatively low molecular weight compound. By this two step swelling process the polymer particles can be brought to absorb more than 100 times their own volume of the low molecular weight compounds to form stable o/w emulsions of the latter, with high oil content, and with a droplet size and size distribution which is completely determined by the size of the polymer particles in the latex applied initially. Monodisperse emulsions with large droplet size could easily be prepared. When the slightly water soluble compound added in the second step is a vinyl monomer which may subsequently be polymerized, the method represents a seed technique which is especially favourable for preparation of latexes with large particles size, including monodisperse latexes, with high solid content.