Macromolecular Chemistry and Physics

Cover image for Vol. 206 Issue 10

May 19, 2005

Volume 206, Issue 10

Pages 981–1063

    1. Cover Picture: Macromol. Chem. Phys. 10/2005 (page 981)

      Tom E. Girardeau, Johannes Leisen and Haskell W. Beckham

      Article first published online: 18 MAY 2005 | DOI: 10.1002/macp.200590018

      Cover: The rotational dynamics of perdeuterated poly(oxyethylene) (POE) confined within nanotubes of stacked cyclodextrins were investigated using 2H solid-state NMR spectroscopy. The experimental 2H NMR lineshapes are shown for some temperatures from 150 to 400 K. These lineshapes were successfully modeled as a three-site discrete jump motion of a C[BOND]2H bond on a cone with an opening angle of 70.5°. Such C[BOND]2H bond reorientations result from exchange between trans, gauche+, and gauche conformations, which can occur in nanotubes as gauche defects travel along the mostly trans POE chains. Further details can be found in the Full Paper by T. E. Girardeau, J. Leisen and H. W. Beckham* on page 998.

    2. Contents: Macromol. Chem. Phys. 10/2005 (pages 983–987)

      Article first published online: 18 MAY 2005 | DOI: 10.1002/macp.200590019

    3. Iridium(III) Complexes with PEO and PS Polymer Macroligands and Light-Emitting Properties: Synthesis and Characterization (pages 989–997)

      Elisabeth Holder, Veronica Marin, Dmitry Kozodaev, Michael A. R. Meier, Bas G. G. Lohmeijer and Ulrich S. Schubert

      Article first published online: 17 MAY 2005 | DOI: 10.1002/macp.200400544

    4. Chain Dynamics of Poly(oxyethylene) in Nanotubes of α-Cyclodextrin by Solid-State 2H NMR (pages 998–1005)

      Tom E. Girardeau, Johannes Leisen and Haskell W. Beckham

      Article first published online: 17 MAY 2005 | DOI: 10.1002/macp.200500095

    5. Polythiophenes Containing Oligo(oxyethylene) Side Chains as a Thin Film on a ZnSe Single Crystal Surface (pages 1006–1014)

      Rick van Beek, Leonardus W. Jenneskens, Aneliya N. Zdravkova, Jan P. J. M. van der Eerden and Cornelis A. van Walree

      Article first published online: 17 MAY 2005 | DOI: 10.1002/macp.200500055

    6. Synthesis and Characterization of Macrocyclic Vinyl-Aromatic Polymers. (pages 1035–1042)

      Kurt A. Alberty, Thieo E. Hogen-Esch and Stephane Carlotti

      Article first published online: 17 MAY 2005 | DOI: 10.1002/macp.200400471

    7. Ethylene–Propylene Copolymerisations: Effect of Metallocene Structure on Termination Reactions and Polymer Microstructure (pages 1043–1056)

      Antti Tynys, Tapio Saarinen, Kimmo Hakala, Tuulamari Helaja, Tiina Vanne, Petri Lehmus and Barbro Löfgren

      Article first published online: 17 MAY 2005 | DOI: 10.1002/macp.200400523

    8. Metathetic Selective Degradation of Polyisoprene: Low-Molecular-Weight Telechelic Oligomer Obtained from Both Synthetic and Natural Rubber (pages 1057–1063)

      Shailendra Singh Solanky, Irène Campistron, Albert Laguerre and Jean-François Pilard

      Article first published online: 17 MAY 2005 | DOI: 10.1002/macp.200400416

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