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Keywords:

  • forced assembly;
  • free volume;
  • interfaces;
  • interphase;
  • nanolayers

Abstract

Thumbnail image of graphical abstract

Atomic force microscopy phase image from the cross-section of a PC/PMMA nanolayer film with 4096 layers and average layer thickness of 25 nm.

When two immiscible polymers are brought into intimate contact, highly localized mixing of polymer chains creates an “interphase” region. Materials that are entirely interphase are fabricated by forced-assembly using layer-multiplying coextrusion to form assemblies of thousands of nanolayers. Analysis of the interphase materials with conventional methods of polymer analysis confirms certain theoretical predictions for the first time. The unique properties of the new interphase materials result from lower free volume than the constituents.