Probing Nanoscale Polymer Interactions by Forced-Assembly

Authors

  • Richard Y. F. Liu,

    1. Department of Macromolecular Science, Case Western Reserve University, 2100 Adelbert Road, Cleveland, OH 44106-7202, USA
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  • Yi Jin,

    1. Department of Macromolecular Science, Case Western Reserve University, 2100 Adelbert Road, Cleveland, OH 44106-7202, USA
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  • Anne Hiltner,

    Corresponding author
    1. Department of Macromolecular Science, Case Western Reserve University, 2100 Adelbert Road, Cleveland, OH 44106-7202, USA
    • Department of Macromolecular Science, Case Western Reserve University, 2100 Adelbert Road, Cleveland, OH 44106-7202, USA. Fax: (+1) 216-368-6329
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  • Eric Baer

    1. Department of Macromolecular Science, Case Western Reserve University, 2100 Adelbert Road, Cleveland, OH 44106-7202, USA
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Abstract

When two immiscible polymers are brought into intimate contact, highly localized mixing of polymer chains creates an “interphase” region. Materials that are entirely interphase are fabricated by forced-assembly using layer-multiplying coextrusion to form assemblies of thousands of nanolayers. Analysis of the interphase materials with conventional methods of polymer analysis confirms certain theoretical predictions for the first time. The unique properties of the new interphase materials result from lower free volume than the constituents.

original image

Atomic force microscopy phase image from the cross-section of a PC/PMMA nanolayer film with 4096 layers and average layer thickness of 25 nm.

Ancillary