‘Click’ Chemistry in Polymer and Materials Science

Authors

  • Wolfgang H. Binder,

    Corresponding author
    1. Vienna University of Technology, Institute of Applied Synthetic Chemistry/Division of Macromolecular Chemistry, Getreidemarkt 9/163/MC, A-1060 Vienna, Austria
    • Vienna University of Technology, Institute of Applied Synthetic Chemistry/Division of Macromolecular Chemistry, Getreidemarkt 9/163/MC, A-1060 Vienna, Austria.
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  • Robert Sachsenhofer

    1. Vienna University of Technology, Institute of Applied Synthetic Chemistry/Division of Macromolecular Chemistry, Getreidemarkt 9/163/MC, A-1060 Vienna, Austria
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Abstract

The modification of polymers after the successful achievement of a polymerization process represents an important task in macromolecular science. Cycloaddition reactions, among them the metal catalyzed azide/alkyne ‘click’ reaction (a variation of the Huisgen 1,3-dipolar cycloaddition reaction between terminal acetylenes and azides) represents an important contribution towards this endeavor. They combine high efficiency (usually above 95%) with a high tolerance of functional groups and solvents, as well as moderate reaction temperatures (25–70 °C). The present review assembles recent literature for applications of this reaction in the field of polymer science (linear polymers, dendrimers, gels) as well as the use of this and related reactions for surface modification on carbon nanotubes, fullerenes, and on solid substrates, and includes the authors own publications in this field. A number of references (>100) are included.

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