Article

Polypropylene surface peroxidation with heterofunctional polyperoxides

  1. Natalya Nosova1,
  2. Yuri Roiter1,
  3. Volodymyr Samaryk1,
  4. Sergiy Varvarenko1,
  5. Yuri Stetsyshyn1,
  6. Sergiy Minko2,
  7. Manfred Stamm2,
  8. Stanislav Voronov1

Article first published online: 4 MAY 2004

DOI: 10.1002/masy.200450638

Issue

Macromolecular Symposia

Macromolecular Symposia

Special Issue: Reactive Polymers 2003

Volume 210, Issue 1, pages 339–348, March 2004

Additional Information

How to Cite

Nosova, N., Roiter, Y., Samaryk, V., Varvarenko, S., Stetsyshyn, Y., Minko, S., Stamm, M. and Voronov, S. (2004), Polypropylene surface peroxidation with heterofunctional polyperoxides. Macromol. Symp., 210: 339–348. doi: 10.1002/masy.200450638

Author Information

  1. 1

    National University “Lvivska Polytechnica”, 12 S. Bandera Str., Lviv 79013, Ukraine

  2. 2

    Institute of Polymer Research, Hohe Strasse 6, D-01069 Dresden, Germany

Publication History

  1. Issue published online: 4 MAY 2004
  2. Article first published online: 4 MAY 2004

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Keywords:

  • covalent grafting;
  • crosslinking;
  • nanolayers;
  • peroxide copolymer;
  • peroxidation of polymer surfaces

Abstract

Method of polyolefin surface activation via covalent grafting of polyperoxide nanolayer by free radical mechanism has been presented. The features of such the nanolayer formation under the thermoprocessing conditions, i.e.: formation of 3D crosslinked network in polyperoxide bulk; and its grafting with complete coating of polyolefin surface, -- is considered. The method provides an availability of uniformly placed peroxide groups of one type over the polyolefin surface activated, which may further be utilized for the tailored modification of polymer surfaces using the “grafting to” and “grafting from” techniques in that time when it is necessary.

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