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Article
NMR Spectroscopy and Atomic Force Microscopy Characterization of Hybrid Organic – Inorganic Coatings
Article first published online: 27 JAN 2005
DOI: 10.1002/masy.200550212
Copyright © 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Issue
1521-3900/asset/cover.gif?v=1&s=8b00f3e1eaf89f5c9e9dfe7beb4bad9a91aff1d5 "Macromolecular Symposia")
Macromolecular Symposia
Special Issue: Spectroscopy of Partially Ordered Macromolecular Systems
Volume 220, Issue 1, pages 155–164, January 2005
Additional Information
How to Cite
Brus, J. and Špírková, M. (2005), NMR Spectroscopy and Atomic Force Microscopy Characterization of Hybrid Organic – Inorganic Coatings. Macromol. Symp., 220: 155–164. doi: 10.1002/masy.200550212
Publication History
- Issue published online: 27 JAN 2005
- Article first published online: 27 JAN 2005
- Abstract
- Cited By
Keywords:
- atomic force microscopy;
- coatings and films;
- solid-state NMR
Abstract
Hybrid organic–inorganic (O-I) epoxide-based products made from functionalized organosilicon precursors, oligomeric di- and triamines and in some cases colloidal silica particles were characterized by NMR spectroscopy and atomic force microscopy (AFM). The kinetics and reaction mechanism of condensation reactions, structure and segmental dynamics of final films, as well as homogeneity and partial ordering were studied by solid-state NMR spectroscopy (2D CRAMPS, 2D 1H-13C WISE, relaxation experiments); the surface morphology and other surface characteristics were determined by AFM.