Article

Advances and Limits in Copolymerization of Olefins with Conjugated Dienes

  1. Christophe Boisson1,
  2. Vincent Monteil1,
  3. Julien Thuilliez1,
  4. Roger Spitz1,
  5. Christiane Monnet2,
  6. Marie-France Llauro2,
  7. Fanny Barbotin3,
  8. Pierre Robert3

Article first published online: 20 JUN 2005

DOI: 10.1002/masy.200550802

Issue

Macromolecular Symposia

Macromolecular Symposia

Special Issue: Polymer Chemistry, Reactions and Processes

Volume 226, Issue 1, pages 17–24, May 2005

Additional Information

How to Cite

Boisson, C., Monteil, V., Thuilliez, J., Spitz, R., Monnet, C., Llauro, M.-F., Barbotin, F. and Robert, P. (2005), Advances and Limits in Copolymerization of Olefins with Conjugated Dienes. Macromol. Symp., 226: 17–24. doi: 10.1002/masy.200550802

Author Information

  1. 1

    Laboratoire de Chimie et Procédés de Polymérisation UMR 140 CNRS/ESCPE, Bât 308 F, 43 Boulevard du 11 Novembre 1918, BP 2077, 69616 Villeurbanne Cedex, France

  2. 2

    Service de RMN de la Fédération des Polyméristes Lyonnais, FR2151/CNRS, 69390 Vernaison, France

  3. 3

    Manufacture Française des Pneumatiques Michelin, 63040 Clermont Ferrand Cedex 9, France

Publication History

  1. Issue published online: 20 JUN 2005
  2. Article first published online: 20 JUN 2005

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Keywords:

  • copolymerization;
  • metallocene;
  • neodymium;
  • poly(ethylene-co-butadiene)

Abstract

The field of the copolymerization of olefins with conjugated dienes has been investigated. While the insertion of butadiene is often limited with most catalyst systems designed for olefin polymerization, lanthanide metallocene catalysts insert butadiene with good efficiency. In the present paper, the preparation of a vast range of products including new polymers is reviewed.

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