• blend;
  • diffusion;
  • reaction;
  • thermosets


Diglycidyl ether of bisphenol A (DGEBA) and 4,4′-methylenebis [2,6-diethylaniline] (MDEA) are miscible in polystyrene at 177 °C. We have studied how their diffusion rate in a molten polystyrene matrix influences their polymerization rate and the morphology of the thermoset particles formed at the end of the reaction. The global composition of the blend was 60 wt% of PS and 40 wt% of epoxy-amine. The diffusional control of the reaction was evidenced by comparing the time of reaction of an initially homogeneous mixture with that of different bi-layer samples. The reaction was controled by the diffusion for relatively thick layers (>0.3. mm). A gradient of morphology was obtained due to the diffusionnal control of the reaction. The asymetricity of this gradient may be explained by three factors: differences in diffusion coefficients, in thermodynamic interactions and in viscosity.