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Article
Syntheses of Special Monomers for π-Conjugated Polymers
Article first published online: 21 JUL 2008
DOI: 10.1002/masy.200850825
Copyright © 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Issue
Macromolecular Symposia
Special Issue: Advanced Polymer Materials for Photonics and Electronics
Volume 268, Issue 1, pages 120–124, July 2008
Additional Information
How to Cite
Výprachtický, D., Cimrová, V., Pavlačková, P. and Kmínek, I. (2008), Syntheses of Special Monomers for π-Conjugated Polymers. Macromol. Symp., 268: 120–124. doi: 10.1002/masy.200850825
Publication History
- Issue published online: 21 JUL 2008
- Article first published online: 21 JUL 2008
Funded by
- Grant Agency of the Academy of Sciences of the Czech Republic. Grant Number: IAA4050409
- Ministry of Education, Youth and Sports of the Czech Republic. Grant Number: 1M06031
- Abstract
- References
- Cited By
Keywords:
- activated ester;
- β-diketone;
- Horner-Wadsworth-Emmons reaction;
- pyrene derivative;
- quinoline derivative;
- substituted thiophene
Abstract
Summary: Tailored monomers based on the activated esters of 2,5-dibromo-benzoic and 2,5-dibromobenzene-1-sulfonic acids or 3-substituted 2,5-dibromothiophene suitable for the Suzuki, Yamamoto or Grignard metathesis (GRIM) coupling reactions were synthesized and characterized by the melting point, elemental analysis, 1H NMR, FT IR, and TLC. The Horner-Wadsworth-Emmons reaction was utilized for the preparation of 3-(arylvinyl)-2,5-dibromothiophenes and the 4-nitrophenol or N-hydroxysuccinimide for the preparation of activated esters. A monomer with β-diketone active structure was prepared and characterized as well.