Kinetic Modeling of ICAR ATRP (pages 52–69)
Dagmar R. D'hooge, Dominik Konkolewicz, Marie-Françoise Reyniers, Guy B. Marin and Krzysztof Matyjaszewski
Article first published online: 3 NOV 2011 | DOI: 10.1002/mats.201100076
ICAR ATRP of methyl methacrylate and styrene is studied as a function of the catalyst reactivity and reaction conditions. The concept of competitive activation/deactivation equilibria is successfully applied to formulate general guidelines allowing the optimization of ICAR processes.