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Figure S1. Spectroscopic data of N-acyl-(hydrolyzed)-fumonisins

Table S1. MS parameters for quantification of N-acyl-FB1-derivatives. The indicated mass to charge ratios (m/z in atomic mass units (amu)) were used for the detection of the molecular ions in quadrupole 1 (Q1) and the respective fragment ions in quadrupole 3 (Q3). Further parameters, namely the collision energy (CE) and the collision cell exit potential were optimized for the multiple reaction monitoring mode, in combination with an ion spray voltage of -4,500 V and declustering potential of -170 eV.

Table S2. Acyl chain distribution of N-acyl-FB1 and N-acyl-HFB1. Data are derived from the same experiment as in Fig. 5. Mean values of FB1- and HFB1-treated samples were normalized to untreated controls (n = 3).

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