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Keywords:

  • NMR;
  • g-factor;
  • micelle;
  • partition constant;
  • nitroxide probe

The use of the ESR g-factor of spin labels for the easy and clean assessment of their partitioning in microheterogeneous media is described. The method constitutes a valuable alternative in those cases where the classical Benesi–Hildebrand treatment, based on UV–visible measurements, is difficult or not feasible. Copyright © 2012 John Wiley & Sons, Ltd.