Get access

Stereostructure of mycoheptin A2

Authors


Jan Pawlak, Gdańsk University of Technology, Chemical Faculty, Department of Pharmaceutical Technology and Biochemistry, Narutowicza St. 11/12, 80-233 Gdańsk, Poland. E-mail: jan.pawlak@wp.pl

Abstract

The absolute configurations of all the stereogenic centers of the antibiotic mycoheptin A2 were established upon previously elaborated general procedure, consisting of DQF-COSY, NOESY, ROESY, HSQC and HMBC experiments as major tools. The structure of mycoheptin A2 without stereochemistry of its aglycone has been reported before. Copyright © 2012 John Wiley & Sons, Ltd.

Ancillary