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Keywords:

  • chromium;
  • fluoride bridges;
  • inorganic polymers;
  • manganese;
  • metal-organic networks
Thumbnail image of graphical abstract

Fluorine is unique! A synthesis method for polynuclear systems with bridging fluorido ligands has been developed. The method is based on anchoring and protection of the fluorido ligand by initial coordination to a robust metal center (e.g., CrIII) and subsequent use of the robust fluoride complex for construction of more complicated polynuclear structures.