Exceptionally good, transparent and flexible FeS2/poly(vinyl pyrrolidone) and FeS2/poly(vinyl alcohol) nanocomposite thin films with excellent UV-shielding properties

Authors

  • Augustine M Sajimol,

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    1. Division for Research in Advanced Materials, Department of Physics, Cochin University of Science and Technology, Kochi—22, Kerala, India
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  • Puthirath B Anand,

    1. Division for Research in Advanced Materials, Department of Physics, Cochin University of Science and Technology, Kochi—22, Kerala, India
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  • Kollery M Anilkumar,

    1. Division for Research in Advanced Materials, Department of Physics, Cochin University of Science and Technology, Kochi—22, Kerala, India
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  • Sankaran Jayalekshmi

    1. Division for Research in Advanced Materials, Department of Physics, Cochin University of Science and Technology, Kochi—22, Kerala, India
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Augustine M Sajimol, Division for Research in Advanced Materials, Department of Physics, Cochin University of Science and Technology, Kochi—22, Kerala, India. E-mail: sajimollazar@gmail.com; sjayakartha@gmail.com

Abstract

Composites of nanocrystalline iron disulfide (FeS2) coated with poly(vinyl pyrrolidone) (PVP) or poly(vinyl alcohol) (PVA) have been successfully synthesized using a solvothermal process, in which PVP and PVA serve as soft templates. Transparent, flexible thin films of these nanocomposites were prepared from homogeneous solution using a solution-casting approach. X-ray diffraction and thermogravimetric analysis and energy-dispersive X-ray, Fourier transform infrared and UV-visible absorption spectroscopic techniques were employed to study the structural and optical properties of these nanocomposite films. UV-visible spectra in transmission mode reveal the UV-shielding efficiency of these nanocomposite films and the films are found to be exceptionally good for UV-shielding applications in the wavelength range 200 to 400 nm. The present work aims at developing transparent and flexible UV-shielding materials and colour filters using cost-effective and non-toxic inorganic–polymer nanocomposites. © 2012 Society of Chemical Industry

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