Article

Phosphorus-containing renewable polyester-polyols via ADMET polymerization: Synthesis, functionalization, and radical crosslinking

  1. Lucas Montero de Espinosa1,
  2. Michael A. R. Meier2,*,
  3. Juan C. Ronda1,*,
  4. Marina Galià1,
  5. Virginia Cádiz1

Article first published online: 18 FEB 2010

DOI: 10.1002/pola.23887

Issue

Journal of Polymer Science Part A: Polymer Chemistry

Journal of Polymer Science Part A: Polymer Chemistry

Volume 48, Issue 7, pages 1649–1660, 1 April 2010

Additional Information

How to Cite

de Espinosa, L. M., Meier, M. A. R., Ronda, J. C., Galià, M. and Cádiz, V. (2010), Phosphorus-containing renewable polyester-polyols via ADMET polymerization: Synthesis, functionalization, and radical crosslinking. Journal of Polymer Science Part A: Polymer Chemistry, 48: 1649–1660. doi: 10.1002/pola.23887

Author Information

  1. 1

    Department of Analytical and Organic Chemistry, Rovira i Virgili University, Campus Sescelades, Marcel.lí Domingo s/n, 43007 Tarragona, Spain

  2. 2

    Laboratory of Sustainable Organic Synthesis, Institute of Chemistry, University of Potsdam, Karl-Liebknecht-Str. 24-25, 14476 Golm/Potsdam, Germany

*Laboratory of Sustainable Organic Synthesis, Institute of Chemistry, University of Potsdam, Karl-Liebknecht-Str. 24-25, 14476 Golm/Potsdam, Germany

Publication History

  1. Issue published online: 18 FEB 2010
  2. Article first published online: 18 FEB 2010
  3. Manuscript Accepted: 14 DEC 2009
  4. Manuscript Received: 30 OCT 2009

Funded by

  • MICINN Ministerio de Ciencia e Innovación. Grant Number: MAT2008-01,412
  • Fachagentur Nachwachsende Rohstoffe. Grant Number: FKZ 22026905

SEARCH

SEARCH BY CITATION

ARTICLE TOOLS

View Full Article (HTML) Get PDF (242K)

Keywords:

  • ADMET;
  • crosslinked polymer;
  • crosslinking;
  • flame retardance;
  • metathesis;
  • polyesters;
  • renewable resources

Graphical Abstract

Thumbnail image of graphical abstract

The acyclic diene metathesis (ADMET) copolymerization of two α,ω-dienes prepared from plant oil derived chemicals, afforded a series of new renewable phosphorus containing linear polyester-polyols. Acrylation of the pendant hydroxyl groups followed by radical polymerization yielded a family of flame retardant crosslinked polymers that have been fully characterized.

Abstract

An α,ω-diene containing hydroxyl groups was prepared from plant oil-derived platform chemicals. The acyclic diene metathesis copolymerization (ADMET) of this monomer with a phosphorus-containing α,ω-diene (DOPO II), also plant oil derived, afforded a series of phosphorus containing linear polyesters, which have been fully characterized. The backbone hydroxyls of these polyesters have been acrylated and radically polymerized to produce crosslinked polymers. The thermomechanical and mechanical properties, the thermal stability, and the flame retardancy of these phosphorus-based thermosets have been studied. Moreover, methyl 10-undecenoate has been used as chain stopper in selected ADMET polymerizations to study the effect of the prepolymers' molecular weights on the different properties of the final materials. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1649–1660, 2010

View Full Article (HTML) Get PDF (242K)