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Article
Dispersion polymerization accompanied by CO2 fixation: Synthesis of particles of polymers bearing cyclic carbonate and epoxide moieties
Article first published online: 5 OCT 2010
DOI: 10.1002/pola.24342
Copyright © 2010 Wiley Periodicals, Inc.
Issue
Journal of Polymer Science Part A: Polymer Chemistry
Volume 48, Issue 23, pages 5382–5390, 1 December 2010
Additional Information
How to Cite
Ochiai, B. and Nakayama, T. (2010), Dispersion polymerization accompanied by CO2 fixation: Synthesis of particles of polymers bearing cyclic carbonate and epoxide moieties. J. Polym. Sci. A Polym. Chem., 48: 5382–5390. doi: 10.1002/pola.24342
Publication History
- Issue published online: 28 OCT 2010
- Article first published online: 5 OCT 2010
- Manuscript Accepted: 20 AUG 2010
- Manuscript Received: 13 APR 2010
- Abstract
- Article
- References
- Cited By
Keywords:
- carbon dioxide;
- dispersions;
- particle;
- radical polymerization;
- synthesis
Abstract
Radical dispersion polymerization of glycidyl methacrylate accompanied by CO2 fixation yielded particles of polymers bearing cyclic carbonate and epoxide moieties in the presence of polymeric dispersion stabilizers. Cellulose acetate successfully stabilized the dispersion, whereas poly(N-vinylpyrrolidone) did not. Spherical particles with diameters of 1–10 μm could be prepared under the optimized conditions. The epoxide moieties in the particle were hydrolyzed selectively keeping the shapes of the particles. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010