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Keywords:

  • metal-polymer complexes;
  • palladium;
  • polyesters;
  • renewable resources
Thumbnail image of graphical abstract

Homo- and heteroleptic Pd(II)-macrocomplexes of different geometries and bearing 4-pyridinemethylene-end-capped polymers of l and rac-lactide were successfully obtained for the first time. The reversible macroligand coordination to Pd(II) was proved to occur in solution.