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Titanium(IV) nonmetallocene complex catalyzed aqueous homopolymerization and copolymerization of styrene and methyl methacrylate: An Environmentally friendly approach to ultrahigh molecular weight polymer nanoparticles

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Abstract

A new titanium(IV) complex bearing [ONO] type ligand has been synthesized, characterized, and employed as catalyst in homopolymerization and copolymerization of styrene and methyl methacrylate. In the presence of sodium tetraphenyl borate and sodium n-dodecyl sulfate (SDS), it exhibits moderate to high activity and afford ultrahigh molecular weight polymers. © 2013 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013

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