Conjugated microporous polymers consisting of tetrasubstituted [2.2]Paracyclophane junctions
Article first published online: 22 FEB 2013
Copyright © 2013 Wiley Periodicals, Inc.
Journal of Polymer Science Part A: Polymer Chemistry
Volume 51, Issue 10, pages 2311–2316, 15 May 2013
How to Cite
Morisaki, Y., Gon, M. and Chujo, Y. (2013), Conjugated microporous polymers consisting of tetrasubstituted [2.2]Paracyclophane junctions. J. Polym. Sci. A Polym. Chem., 51: 2311–2316. doi: 10.1002/pola.26600
- Issue published online: 5 APR 2013
- Article first published online: 22 FEB 2013
- Manuscript Accepted: 24 JAN 2013
- Manuscript Received: 18 DEC 2012
- conjugated polymers;
Conjugated microporous polymers (CMPs) were synthesized from the tetrasubstituted [2.2]paracyclophane skeleton as a tetra-functional building block using Hay coupling, Sonogashira–Hagihara cross-coupling, and Yamamoto coupling. The CMPs exhibited microporosity (less than 2 nm) and large surface areas (up to approximately 1000 m2 g–1). The CMPs consisted of relatively uniform particles and dispersed in organic solvents.