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Keywords:

  • block copolymers;
  • nonconjugated monomer;
  • poly(N-isopropylacrylamide);
  • reversible addition-fragmentation chain transfer polymerization;
  • stimuli-sensitive polymers;
  • thermo-responsive materials
Thumbnail image of graphical abstract

New route for synthesize block copolymers containing poly(N-isopropylacrylamide) backbone and polyvinyl acetate or poly(N-vinyl-2-pyrrolidone) side chains is developed. The side-chain density and length can be adjusted with the benefit of using living radical polymerization method.