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Article
Synthesis of poly(1-oxodimethylene) via oxidation of poly(vinyl alcohol) with a hydrogen peroxide/hydrobromic acid system and metal complexation behavior of poly(1-oxodimethylene)
Article first published online: 15 MAR 2013
DOI: 10.1002/pola.26647
Copyright © 2013 Wiley Periodicals, Inc.
Issue
Journal of Polymer Science Part A: Polymer Chemistry
Volume 51, Issue 12, pages 2598–2605, 15 June 2013
Additional Information
How to Cite
Kinemuchi, H. and Ochiai, B. (2013), Synthesis of poly(1-oxodimethylene) via oxidation of poly(vinyl alcohol) with a hydrogen peroxide/hydrobromic acid system and metal complexation behavior of poly(1-oxodimethylene). J. Polym. Sci. A Polym. Chem., 51: 2598–2605. doi: 10.1002/pola.26647
Publication History
- Issue published online: 11 MAY 2013
- Article first published online: 15 MAR 2013
- Manuscript Accepted: 7 FEB 2013
- Manuscript Revised: 4 FEB 2013
- Manuscript Received: 7 DEC 2012
- Abstract
- Article
- References
- Cited By
Keywords:
- metal-free oxidation;
- metal-polymer complexes;
- networks;
- oxidation;
- recycling
ABSTRACT
Poly(1-oxodimethylene) was synthesized via oxidation of poly(vinyl alcohol) with a hydrogen peroxide/hydrobromic acid system. The content of the carbonyl groups in poly(1-oxodimethylene) depended on the amount of water added, and lower amounts of water were suitable for efficient oxidation due to higher acidity of the reaction system. The highest content of carbonyl groups was estimated to be above 88% by the titration with hydrazine that reacted with the carbonyl groups in poly(1-oxodimethylene). The obtained poly(1-oxodimethylene) complexed with Cu and Ni ions under basic conditions. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 2598–2605