Article

Selenium-substituted carbonates as mediators for controlled radical polymerization

  1. Jindong Zeng,
  2. Zhengbiao Zhang,
  3. Jian Zhu*,
  4. Nianchen Zhou,
  5. Zhenping Cheng,
  6. Xiulin Zhu*

Article first published online: 15 MAR 2013

DOI: 10.1002/pola.26648

Issue

Journal of Polymer Science Part A: Polymer Chemistry

Journal of Polymer Science Part A: Polymer Chemistry

Volume 51, Issue 12, pages 2606–2613, 15 June 2013

Additional Information

How to Cite

Zeng, J., Zhang, Z., Zhu, J., Zhou, N., Cheng, Z. and Zhu, X. (2013), Selenium-substituted carbonates as mediators for controlled radical polymerization. J. Polym. Sci. A Polym. Chem., 51: 2606–2613. doi: 10.1002/pola.26648

Author Information

  1. Department of Polymer Science and Engineering, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, People's Republic of China

*Correspondence to: J. Zhu (E-mail: chemzhujian@suda.edu.cn) or X. Zhu (E-mail: xlzhu@suda.edu.cn)

Publication History

  1. Issue published online: 11 MAY 2013
  2. Article first published online: 15 MAR 2013
  3. Manuscript Accepted: 4 FEB 2013
  4. Manuscript Revised: 1 FEB 2013
  5. Manuscript Received: 30 OCT 2012

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Figure S1. Evolution of GPC traces of the prepared PS-TTC.

Figure S2. Evolution of GPC traces of the prepared PS-DTSC.

Figure S3. Evolution of GPC traces of the prepared PS-TDSC.

Figure S4. Evolution of GPC traces of the prepared PS-TSC.

Figure S5.1H NMR full spectra of PS-TTC obtained from TTC (Mn,GPC = 9700, Mw/Mn = 1.26) in CDCl3.

Figure S6.1H NMR full spectra of PS-DTSC obtained from DTSC (Mn,GPC = 10500, Mw/Mn = 1.17) in CDCl3.

Figure S7.1H NMR full spectra of PS-TDSC obtained from TDSC (Mn,GPC = 5800, Mw/Mn = 1.24) in CDCl3.

Figure S8.1H NMR spectra of PS-DTSC after oxidative homolysis. (Mn,GPC= 5900 g/mol, Mw/Mn= 1.17) with CDCl3 as the solvent.

Figure S9.1H NMR spectra of PS-TDSC after oxidative homolysis. (Mn,GPC= 8100 g/mol, Mw/Mn= 1.26) with CDCl3 as the solvent.

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