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FIGURE S1 Plots of monomer conversion (■) and PDI (○) of the resultant polymers with reaction time.

FIGURE S2 Molecular weight vs retention volume curves for linear PMMA and hyperbranched copolymers of entries 2, 3, 4, and 6 in Table 3

FIGURE S3 Plots of Mn (■ the determined Mn, ● the theoretical Mn) and PDI (○) of the resultant copolymers with monomer conversion.

FIGURE S4 Quantitative 13C NMR spectrum of the resultant copolymers.

FIGURE S5 FTIR spectra of PMMA-type copolymer (before) and epoxidation functionalized polymer (after)

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