RAFT polymerization of a novel allene-derived asymmetrical divinyl monomer: A facile strategy to alkene-functionalized hyperbranched vinyl polymers with high degrees of branching
Article first published online: 9 APR 2013
Copyright © 2013 Wiley Periodicals, Inc.
Journal of Polymer Science Part A: Polymer Chemistry
Volume 51, Issue 13, pages 2959–2969, 1 July 2013
How to Cite
Bao, Y., Shen, G., Liu, X. and Li, Y. (2013), RAFT polymerization of a novel allene-derived asymmetrical divinyl monomer: A facile strategy to alkene-functionalized hyperbranched vinyl polymers with high degrees of branching. J. Polym. Sci. A Polym. Chem., 51: 2959–2969. doi: 10.1002/pola.26693
- Issue published online: 30 MAY 2013
- Article first published online: 9 APR 2013
- Manuscript Accepted: 13 MAR 2013
- Manuscript Received: 16 OCT 2012
- National Natural Science Foundation of China. Grant Numbers: 20923003, 21074127
Additional Supporting Information may be found in the online version of this article.
FIGURE S1 Plots of monomer conversion (■) and PDI (○) of the resultant polymers with reaction time.
FIGURE S2 Molecular weight vs retention volume curves for linear PMMA and hyperbranched copolymers of entries 2, 3, 4, and 6 in Table 3
FIGURE S3 Plots of Mn (■ the determined Mn, ● the theoretical Mn) and PDI (○) of the resultant copolymers with monomer conversion.
FIGURE S4 Quantitative 13C NMR spectrum of the resultant copolymers.
FIGURE S5 FTIR spectra of PMMA-type copolymer (before) and epoxidation functionalized polymer (after)
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