Formation of a porphyrin/fullerene light-harvesting system from self-assembly of porphyrin-end-functionalized polycyclohexane and [6,6]-phenyl-C61-butyric acid methyl ester: Effects of microphase separation and π–π interactions

Authors

  • Itaru Natori,

    Corresponding author
    1. Chemical and Material Systems, Graduate School of Bio-Applications and Systems Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Naka-chou, Koganei City, Tokyo 184-8588, Japan
    • Chemical and Material Systems, Graduate School of Bio-Applications and Systems Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Naka-chou, Koganei City, Tokyo 184-8588, Japan
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  • Shizue Natori,

    1. Chemical and Material Systems, Graduate School of Bio-Applications and Systems Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Naka-chou, Koganei City, Tokyo 184-8588, Japan
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  • Anna Kanasashi,

    1. Chemical and Material Systems, Graduate School of Bio-Applications and Systems Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Naka-chou, Koganei City, Tokyo 184-8588, Japan
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  • Kosuke Tsuchiya,

    1. Chemical and Material Systems, Graduate School of Bio-Applications and Systems Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Naka-chou, Koganei City, Tokyo 184-8588, Japan
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  • Kenji Ogino

    1. Chemical and Material Systems, Graduate School of Bio-Applications and Systems Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Naka-chou, Koganei City, Tokyo 184-8588, Japan
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Abstract

Thin films composed of zinc tetraphenylporphyrin-end-functionalized polycyclohexane (ZnTPP-PCHE) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) blends were prepared to investigate their potential as light-harvesting systems within polymer solar cells (PSCs). Both the microphase separation characteristics and the extent of π–π interactions in these ZnTPP-PCHE/PCBM blends had significant effects on the optical properties of the films. The extent to which the absorption bands of the films overlapped the terrestrial solar spectrum was increased considerably when the blends formed a co-continuous structure, even though films of pure ZnTPP-PCHE or PCBM exhibited only weak absorption over that wavelength region. We conclude that these polymer blend films may be considered as viable candidates for light-harvesting systems within PSCs. © 2012 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2013

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