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Keywords:

  • Non-Hermitian Hamiltonian;
  • Wigner-Smith delay times;
  • scattering of HOCl system.

Abstract

We construct the scattering matrix for a two-dimensional model of a Cl atom scattering from an OH dimer. We show that the scattering matrix can be written in terms of a non-Hermitian Hamiltonian whose complex energy eigenvalues can be used to compute Wigner-Smith delay times for the Cl-OH scattering process. We compute the delay times for a range of energies, and show that the scattering states with the longest delay times are strongly influenced by unstable periodic orbits in the classical dynamics.