Prepared for presentation at AIChE Spring Meeting, Atlanta, GA, April 10–14, 2005.
Article first published online: 8 JUL 2005
Copyright © 2005 American Institute of Chemical Engineers (AIChE)
Process Safety Progress
Volume 24, Issue 3, pages 203–212, September 2005
How to Cite
de Hemptinne, J.-C. (2005), Benzene crystallization risks in the LIQUEFIN liquefied natural gas process. Proc. Safety Prog., 24: 203–212. doi: 10.1002/prs.10084
AIChE shall not be responsible for statements or opinions contained in papers or printed in its publications.
- Issue published online: 1 AUG 2005
- Article first published online: 8 JUL 2005
In liquefied natural gas (LNG) processes, the gas feed is cooled to very low temperatures (−160° C). The presence of traces of heavy hydrocarbon components may therefore result in crystallization, and thus equipment plugging. The present work investigates the solid–liquid–vapor equilibria and proposes a way to predict the risks of crystallization.
In the first section, the phase diagrams that may be encountered with natural gas mixtures at these very low temperatures are presented. A literature review shows that few data are available for operating conditions of LNG processes.
In the second section, the crystallization model based on a cubic equation of state, coupled with a Huron–Vidal mixing rule and combined with a solid-phase model is presented. This model requires the crystallization heat capacity of pure components, which must be determined using the few data points available. Nevertheless, it appears that the resulting model is rather predictive when compared to data that were not used in the regression.
Finally, the model is applied in different zones of the LIQUEFIN process, commercialized by AXENS. The results have been used to improve the design of this LNG plant. © 2005 American Institute of Chemical Engineers Process Saf Prog, 2005