Presented at the 2nd Joint European Stable Isotope User Meeting (JESIUM), Presqu'île de Giens, France, 31 August–5 September, 2008.
Special Issue Paper
On the application of a ZrO2-based solid electrolyte in isotope ratio mass spectrometry†
Article first published online: 14 JUL 2009
Copyright © 2009 John Wiley & Sons, Ltd.
Rapid Communications in Mass Spectrometry
Volume 23, Issue 16, pages 2461–2466, 30 August 2009
How to Cite
Galimov, E. M., Sevastyanov, V. S., Babulevich, N. E. and Tyurina, E. N. (2009), On the application of a ZrO2-based solid electrolyte in isotope ratio mass spectrometry. Rapid Commun. Mass Spectrom., 23: 2461–2466. doi: 10.1002/rcm.4055
- Issue published online: 14 JUL 2009
- Article first published online: 14 JUL 2009
- Manuscript Accepted: 30 MAR 2009
- Manuscript Revised: 27 MAR 2009
- Manuscript Received: 16 DEC 2008
The application of a high-temperature electrochemical reactor based on stabilized zirconium dioxide (0.9 ZrO20.1 Y2O3) for organic gas sampling in continuous-flow isotope-ratio mass spectrometry (CF-IRMS) has been found to be efficient. This solid electrolyte reactor (SER) can also be used as a chromatographic detector for the quantitative measurements of organic gases. A three-electrode SER system was studied. Complete stoichiometric oxidation of organic gases has been achieved at 900–950°C due to the large catalytic surface area of the porous platinum coating. At this temperature, the oxygen ions formed from the oxygen of ambient air on the outer surface of the reactor migrate through the solid electrolyte under the action of the applied electric field and allow combustion of gases being analyzed to be effected. It should be noted that oxygen gas was not introduced into the gas-carrier flow. Similar results for the measurements of carbon isotope ratios were obtained at the oxidation of hydrocarbon gases in both the standard and the solid electrolyte reactors. Copyright © 2009 John Wiley & Sons, Ltd.