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Characterization of tetrathiofulvalene compounds using matrix-assisted laser desorption/ionization time-of-flight mass spectrometry

Authors

  • Shaoxiang Xiong,

    Corresponding author
    1. Beijing Mass Spectrometry Center, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China
    • Beijing Mass Spectrometry Center, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China.
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  • Dan Pu,

    1. Beijing Mass Spectrometry Center, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China
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  • Bin Xin,

    1. Beijing Mass Spectrometry Center, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China
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  • Guanghui Wang

    1. Beijing Mass Spectrometry Center, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China
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Abstract

Tetrathiofulvalene compounds are important components of charge-transfer complexes, which may be applied in various fields of scientific research and practical applications. Some of these compounds cannot be characterized by mass spectrometry. Here, matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF) mass spectrometry was used for the characterization of tetrathiofulvalenes. The samples could be easily desorbed and ionized to form singly charged ions, and mass spectra with isotopic resolution readily obtained. The mass spectrometric results for 26 compounds have shown that MALDI-TOF is more effective and convenient than other mass spectrometry methods, and resolves the problem of mass spectrometric characterization of tetrathiofulvalene compounds. Copyright © 2001 John Wiley & Sons, Ltd.

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