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Estimation of useful yields for electrospray droplet impact/secondary ion mass spectrometry (EDI/SIMS)

Authors


Correspondence to: Kenzo Hiraoka, Clean Energy Research Center, University of Yamanashi, Kofu, 400-8511, Japan.

E-mail: hiraoka@yamanashi.ac.jp

Abstract

Useful yield for electrospray droplet impact/secondary ion mass spectrometry was estimated. The mixtures of C60/rhodamine B and C60/Aerosol OT were used as the samples for the positive and negative mode of operations, respectively. By assuming that (i) the desorption efficiencies are about the same for C60, rhodamine B and Aerosol OT, and (ii) desorption of ionic compounds directly gives the secondary ion signals, the useful yields (i.e. total ions generated divided by the total molecules desorbed) for C60 were estimated to be ~0.1. This value should be regarded as the upper limit because the neutralization of positive and negative ions in the plume and desorption of ionic compounds as neutral species are not taken into account. Copyright © 2012 John Wiley & Sons, Ltd.

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