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Keywords:

  • fullerenes;
  • nanostructures;
  • self-assembly;
  • surfaces;
  • templates
Thumbnail image of graphical abstract

Highly ordered linear C60 molecular-chain arrays with 2.31-nm interchain spacing (see image) are self-assembled on Ag(111) by using α-sexithiophene (6T) monolayer nanostripes on Ag(111) as a molecular surface nanotemplate. The subtle balance between molecule–molecule and molecule–substrate interactions facilitates the assembly of the C60 into well-ordered molecular-chain arrays.