Direct Growth of Polyaniline Chains from N-Doped Sites of Carbon Nanotubes

Authors

  • Atta Ul Haq,

    1. Center for Nanomaterials and Chemical Reactions, Institute for Basic Science (IBS), Department of Materials Science and Engineering, KAIST, Daejeon 305-701, S. Korea
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  • Joonwon Lim,

    1. Center for Nanomaterials and Chemical Reactions, Institute for Basic Science (IBS), Department of Materials Science and Engineering, KAIST, Daejeon 305-701, S. Korea
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  • Je Moon Yun,

    1. Center for Nanomaterials and Chemical Reactions, Institute for Basic Science (IBS), Department of Materials Science and Engineering, KAIST, Daejeon 305-701, S. Korea
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  • Won Jun Lee,

    1. Center for Nanomaterials and Chemical Reactions, Institute for Basic Science (IBS), Department of Materials Science and Engineering, KAIST, Daejeon 305-701, S. Korea
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  • Tae Hee Han,

    Corresponding author
    1. Department of Organic and Nano Engineering, Hanyang University, Seoul 133-791, S. Korea
    • Tae Hee Han, Department of Organic and Nano Engineering, Hanyang University, Seoul 133-791, S. Korea.

      Sang Ouk Kim, Center for Nanomaterials and Chemical Reactions, Institute for Basic Science (IBS), Department of Materials Science and Engineering, KAIST, Daejeon 305-701, S. Korea

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  • Sang Ouk Kim

    Corresponding author
    1. Center for Nanomaterials and Chemical Reactions, Institute for Basic Science (IBS), Department of Materials Science and Engineering, KAIST, Daejeon 305-701, S. Korea
    • Tae Hee Han, Department of Organic and Nano Engineering, Hanyang University, Seoul 133-791, S. Korea.

      Sang Ouk Kim, Center for Nanomaterials and Chemical Reactions, Institute for Basic Science (IBS), Department of Materials Science and Engineering, KAIST, Daejeon 305-701, S. Korea

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Abstract

Polymer grafting from graphitic carbon materials has been pursued for several decades. Unfortunately, currently available methods mostly rely on the harsh chemical treatment of graphitic carbons which causes severe degradation of chemical structure and material properties. A straightforward growth of polyaniline chain from the nitrogen (N)-doped sites of carbon nanotubes (CNTs) is presented. N-doping sites along the CNT wall nucleate the polymerization of aniline, which generates seamless hybrids consisting of polyaniline directly grafted onto the CNT walls. The resultant materials exhibit excellent synergistic electrochemical performance, and can be employed for charge collectors of supercapacitors. This approach introduces an efficient route to hybrid systems consisting of conducting polymers directly grafted from graphitic dopant sites.

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