Article

Synthesis and Structure of Potassium 1-Benzylimidazole-2-carboxylate · 2/3Hydrate

  1. Michael P. Batten1,
  2. Allan J. Canty Prof.1,*,
  3. Kingsley J. Cavell1,2,
  4. Brian W. Skelton3,
  5. Allan H. White3

Article first published online: 27 FEB 2006

DOI: 10.1002/zaac.200500519

Issue

Zeitschrift für anorganische und allgemeine Chemie

Zeitschrift für anorganische und allgemeine Chemie

Volume 632, Issue 4, pages 655–658, March 2006

Additional Information

How to Cite

Batten, M. P., Canty, A. J., Cavell, K. J., Skelton, B. W. and White, A. H. (2006), Synthesis and Structure of Potassium 1-Benzylimidazole-2-carboxylate · 2/3Hydrate. Zeitschrift für anorganische und allgemeine Chemie, 632: 655–658. doi: 10.1002/zaac.200500519

Author Information

  1. 1

    Hobart/Australia, School of Chemistry, University of Tasmania

  2. 2

    Current address: Cardiff/UK, Department of Chemistry, Cardiff University

  3. 3

    Perth/Australia, School of Biomedical, Biomolecular and Chemical Sciences, University of Western Australia

*University of Tasmania, School of Chemistry, Hobart, 7001 Tasmania, Fax +61 3 6226-2858

Publication History

  1. Issue published online: 27 FEB 2006
  2. Article first published online: 27 FEB 2006
  3. Manuscript Received: 9 DEC 2005

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Keywords:

  • Potassium;
  • Imidazole;
  • Benzimidazole;
  • Benzimidazole carboxylate;
  • Bidentate Ligand;
  • Crystal Structure

Abstract

The title compound, K[bimCO2] · 2/3H2O (C11H19N2O2K · 2/3H2O), has been synthesized, and characterized by a single crystal X-ray study; it has the grouping equation imagecross-linked into a polymeric sheet in which potassium environments are diverse and unsymmetrical, containing six-coordinate and seven-coordinate geometries.

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