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Keywords:

  • Zinc;
  • N-Ligands;
  • Structure elucidation

Abstract

The reaction of 1,2-bis[(trimethylsilyl)imino]acenaphthene (1, tms-BIAN) with ZnCl2 and ZnI2 in THF and Et2O afford (tms-BIAN)ZnCl2 (2) and (tms-BIAN)ZnI2 (3), respectively. The compounds 2 and 3 were characterized by IR- and NMR spectroscopy as well as by single crystal X-ray analysis.