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Article
Ferrocene Derivatives Bearing one and two Isocyanato, Isothiocyanato and Isoselenocyanato Substituents†
Article first published online: 26 MAY 2008
DOI: 10.1002/zaac.200800133
Copyright © 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Issue
Zeitschrift für anorganische und allgemeine Chemie
Volume 634, Issue 8, pages 1434–1438, July 2008
Additional Information
How to Cite
Wrackmeyer, B., Maisel, H. E., Milius, W. and Herberhold, M. (2008), Ferrocene Derivatives Bearing one and two Isocyanato, Isothiocyanato and Isoselenocyanato Substituents. Zeitschrift für anorganische und allgemeine Chemie, 634: 1434–1438. doi: 10.1002/zaac.200800133
- †
Publication History
- Issue published online: 26 MAY 2008
- Article first published online: 26 MAY 2008
- Manuscript Accepted: 25 MAR 2008
- Manuscript Received: 20 FEB 2008
- Abstract
- References
- Cited By
Keywords:
- Ferrocenes;
- Isocyanates;
- Isothiocyanates;
- Isoselenocyanates;
- Crystal structures;
- NMR (multinuclear) spectroscopy
Abstract
Isocyanato- (1a), 1,1′-di(isocyanato)- (2a), isothiocyanato- (1b), 1,1′-di(isothiocyanato)- (2b), isoselenocyanato- (1c) and 1,1′-di(isoselenocyanato)ferrocene (2c) were prepared and studied by 1H, 13C and 14N NMR spectroscopy. Isocyanatoferrocene (1a) trimerizes upon chromatography on alumina to give 3a. The molecular structures of 2c and 3a were determined by X-ray analysis, and almost undistorted ferrocene-like structures were found in both cases.