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Keywords:

  • Hypervalent compounds;
  • Silicon;
  • Isomers;
  • Spiro compounds;
  • Chirality

Abstract

In this research report, we explore the emerging field of stable pentaorganosilicates, with the aim to show the development from transient species to stable and configurationally rigid analogues that may find application e.g. as novel chiral auxiliaries or in chiral ionic liquids.