A lvt-type Framework [Cu2(tza)4]·ClO4·4H2O Derived from 1H-tetrazole-1-acetic Acid

Authors

  • Li Ma,

    1. School of Chemistry and Environment, South China Normal University, Guangzhou 510006 P. R. China
    2. Key Lab of Electrochemical Technology on Energy Storage and Power Generation in Guangdong Universities, Guangzhou 510631, P. R. China
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  • Guo Peng,

    1. School of Chemistry and Environment, South China Normal University, Guangzhou 510006 P. R. China
    2. Key Lab of Electrochemical Technology on Energy Storage and Power Generation in Guangdong Universities, Guangzhou 510631, P. R. China
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  • Jin-Biao Cai,

    1. School of Chemistry and Environment, South China Normal University, Guangzhou 510006 P. R. China
    2. Key Lab of Electrochemical Technology on Energy Storage and Power Generation in Guangdong Universities, Guangzhou 510631, P. R. China
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  • Dr. Hong Deng,

    Corresponding author
    1. School of Chemistry and Environment, South China Normal University, Guangzhou 510006 P. R. China
    2. Key Lab of Electrochemical Technology on Energy Storage and Power Generation in Guangdong Universities, Guangzhou 510631, P. R. China
    • , Fax: +86-20-39310187
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  • Matthias Zeller

    Corresponding author
    1. Department of Chemistry, Youngstown State University, One University Plaza, Youngstown Ohio 44555–3663, USA
    • Department of Chemistry, Youngstown State University, One University Plaza, Youngstown Ohio 44555–3663, USA
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Errata

This article is corrected by:

  1. Errata: Erratum: A lvt-Type Framework [Cu2(tza)4]·ClO4·4H2O Derived from 1H-Tetrazole-1-Acetic Acid Volume 637, Issue 10, 1271, Article first published online: 26 July 2011

  • Supporting information for this article is available on the WWW under http://dx.doi.org/10.1002/zaac.201000454 or from the author.

Abstract

The reaction of 1H-tetrazole-1-acetic acid (Htza) and perchloric acid with cuprous chloride with slow evaporation at room temperature gave a novel 3D porous CuII coordination polymer, [Cu2(tza)4]·ClO4·4H2O (1), (tza = tetrazole-1-acetate). The structure exhibits an unusual 3D microporous coordination framework built up by four coordinated CuII nodes and bidentate bridging tza ligands with lvt-type topology. Furthermore, the magnetic properties of complex 1 were also investigated.

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