Synthesis, Crystal Structure, and Properties of the 3D Porous Framework [Zn(INAIP)]·DMA·H2O

Authors

  • Dr. Man-Sheng Chen,

    Corresponding author
    1. Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan, 421008 P. R. China
    • Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan, 421008 P. R. China, Fax: +86-734-8484911
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  • Xiong-Wen Tan,

    1. Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan, 421008 P. R. China
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  • Dr. Chun-Hua Zhang,

    Corresponding author
    1. Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan, 421008 P. R. China
    • Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan, 421008 P. R. China
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  • Dai-Zhi Kuang

    1. Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan, 421008 P. R. China
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  • Supporting information for this article is available on the WWW under http://dx.doi.org/10.1002/zaac.201100082 or from the author.

Abstract

A new three-dimensional (3D) porous framework [Zn(INAIP)]·DMA·H2O (1) [INAIP = 5-(isonicotinamido)isophthalate, DMA = N,N′-dimethylacetamide] was synthesized by solvothermal methods and characterized by single-crystal and powder X-ray diffraction, as well as thermogravimetric analysis. The results of X-ray diffraction analyses revealed that complex 1 has an unusual 3D architecture with the (3,6)-connected rutile (rtl) topology. The adsorption behavior shows that compound 1 exhibits selective adsorptions of CO2 over N2 after the removal of the solvent molecules within the pores.

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