A New Zinc(II) Coordination Polymer with a Threefold-Interpenetrating Diamondoid Net: Synthesis, Crystal Structure and Luminescent Property

Authors

  • Hui Miao,

    1. College of Chemistry and Chemical Engineering, Fuyang Teachers College, Fuyang, Anhui 236041, P. R. China
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  • Yumin Cui,

    Corresponding author
    1. College of Chemistry and Chemical Engineering, Fuyang Teachers College, Fuyang, Anhui 236041, P. R. China
    • Yumin Cui, College of Chemistry and Chemical Engineering, Fuyang Teachers College, Fuyang, Anhui 236041, P. R. China

      Feng Guo, Key Laboratory of Coordination Chemistry and Functional Materials in Universities of Shandong, Dezhou University, Shandong 253023, P. R. China

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  • Feng Guo

    Corresponding author
    1. Key Laboratory of Coordination Chemistry and Functional Materials in Universities of Shandong, Dezhou University, Shandong 253023, P. R. China
    • Yumin Cui, College of Chemistry and Chemical Engineering, Fuyang Teachers College, Fuyang, Anhui 236041, P. R. China

      Feng Guo, Key Laboratory of Coordination Chemistry and Functional Materials in Universities of Shandong, Dezhou University, Shandong 253023, P. R. China

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Abstract

The three-dimensional (3D) coordination polymer, [Zn(dpa)(bib)]n (1) [H2dap = diaphonic acid and bib = 1,4-bis(imidazol-1-yl)benzene], was prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, FT-IR spectroscopy, XRPD, and elemental analysis. Crystal structure determination revealed that complex 1 shows a threefold diamond topological net. Furthermore, the solid-state luminescent property of [Zn(dpa)(bib)]n was investigated.

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