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Syntheses and Characterization of Polyfunctional Organotin Chlorides

Authors

  • Jens P. Eußner,

    1. Fachbereich Chemie and, Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Philipps-Universität Marburg, Hans-Meerwein-Straße, 35043 Marburg, Germany
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  • Stefanie Dehnen

    Corresponding author
    1. Fachbereich Chemie and, Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Philipps-Universität Marburg, Hans-Meerwein-Straße, 35043 Marburg, Germany
    • Fachbereich Chemie and, Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Philipps-Universität Marburg, Hans-Meerwein-Straße, 35043 Marburg, Germany, Fax: +49-6421-28 25653

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  • Dedicated to Professor Bernt Krebs on the Occasion of His 75th Birthday

  • Supporting Information for this article is available on the WWW under http://dx.doi.org/10.1002/zaac.201300573 or from the author.

Abstract

We report the syntheses and crystal structures of novel organotin chloride complexes with functional organic substituents from HSnCl3·2Et2O (13). Whereas Cl3SnCHPhCH2C(O)(CH)2Ph (1) was synthesized in a traditional route from HSnCl3·2Et2O and dibenzylideneacetone, C6H5Cl5O4Sn2 (2) and C8H9Cl5O4Sn2 (3) represent products of a condensation reaction of mononuclear organotintrichlorides that comprise both C=C and C=O functional groups and additionally exhibit characteristic intramolecular donor-acceptor interactions. Due to the condensation, compounds 2 and 3 combine SnCl2 with SnCl3 groups within one molecule.

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