Zeitschrift für anorganische und allgemeine Chemie

Cover image for Vol. 639 Issue 10

August 2013

Volume 639, Issue 10

Pages 1685–1891

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      Cover Picture: ZAAC - Journal of Inorganic and General Chemistry 10/2013 (page 1685)

      Version of Record online: 1 AUG 2013 | DOI: 10.1002/zaac.201390023

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      The cover picture shows the structural formula of the new N-heterocyclic carbene (NHC) “4,5-dicyano-1,3-dimesitylimidazol-2-ylidene” (middle) and the X-ray structures of its precursor 4,5-dicyano-1,3-dimesityl-2-(pentafluorophenyl)-2,3-dihydroimidazole (bottom), the [AgCl(NHC)]-complex (top) on the left side and the [RhCl(COD)(NHC)]-complex (top) and [RhCl(CO)2(NHC)]-complex (bottom) on the right side. For the first time, a 1,3-diarylated 4,5-dicyanoimidazoline could be synthesized. Via thermolysis of the imidazoline, the corresponding [AgCl(NHC)]-complex could be formed and used as transmetallation agent for the preparation of the [RhCl(COD)(NHC)]- and the [RhCl(CO)2(NHC)]-complex. The sterical demand of the new NHC was determined using the crystallographic data of the RhI complexes and the electronic properties could be calculated from infrared spectroscopic data of the [RhCl(CO)2(NHC)]-complex by determination of the Tolman Electronic Parameter. More details are discussed in the article by H.-J. Holdt et al. on page 1731 ff.

  2. Contents

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    2. Cover Picture
    3. Contents
    4. Review
    5. Short Communications
    6. Articles
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  3. Review

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  4. Short Communications

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    1. Reactions of Titanocene with Triazines and Dicyandiamide: Formation of Novel Di- and Trinuclear Metallacyclic Complexes (pages 1717–1721)

      Martin Ruhmann, Anke Spannenberg, Alexander Villinger, Axel Schulz and Torsten Beweries

      Version of Record online: 1 JUL 2013 | DOI: 10.1002/zaac.201300226

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    2. The New Homoleptic Tetracyanamidoaluminate LiBa2[Al(CN2)4] (pages 1722–1725)

      Leonid Unverfehrt, Markus Ströbele and H.-Jürgen Meyer

      Version of Record online: 10 JUL 2013 | DOI: 10.1002/zaac.201300284

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    3. A Luminescent Silver(I) Metal-Organic Framework with New (4,6)-Connected Topology Based on Mixed Tetrachlorotereph­thalate and 2,2′-Bipyridine Ligands (pages 1726–1730)

      Sheng-Chun Chen, Xiao-Xiao Cai, Zhi-Hui Zhang, Qi Yan, Ming-Yang He, Feng Tian, Jian Gao and Qun Chen

      Version of Record online: 8 JUL 2013 | DOI: 10.1002/zaac.201300242

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  5. Articles

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    1. Rhodium(I) and Silver(I) Complexes of 4, 5-Dicyano-1, 3-dimesityl- and 4, 5-Dicyano-1, 3-dineopentylimidazol-2-ylidene (pages 1731–1739)

      Heiko Baier, Alexandra Kelling, Ralf Jackstell and Hans-Jürgen Holdt

      Version of Record online: 16 JUL 2013 | DOI: 10.1002/zaac.201300250

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    2. Energetic Materials Based on the 5-Azido-3-nitro-1, 2,4-tri­azolate Anion (pages 1746–1755)

      Dániel Izsák, Thomas M. Klapötke, Regina Scharf and Jörg Stierstorfer

      Version of Record online: 4 JUN 2013 | DOI: 10.1002/zaac.201300203

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    3. Synthesis and Crystal Structure of the Azide K4[Re6Sei8(N3)a6]·4H2O; Luminescence, Redox, and DFT Investigations of the [Re6Sei8(N3)a6]4– Cluster Unit (pages 1756–1762)

      Aurore Gandubert, Konstantin A. Brylev, Thi Thuong Nguyen, Nikolai G. Naumov, Noboru Kitamura, Yann Molard, Régis Gautier and Stéphane Cordier

      Version of Record online: 17 JUN 2013 | DOI: 10.1002/zaac.201300151

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    4. A New Iron(II) Complex with Strongly Saddle Shaped Schiff Base like Ligand (pages 1763–1767)

      Stephan Schlamp, Peter Thoma, Tobias Bauer, Rhett Kempe and Birgit Weber

      Version of Record online: 2 JUL 2013 | DOI: 10.1002/zaac.201300176

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    5. Electrochemical and Biological Studies on Reactivity of [VO(oda)(H2O)2], [Co(oda)(H2O)2]·H2O, and [Ni(oda)­(H2O)3]·1.5H2O Towards Superoxide Free Radicals (pages 1795–1799)

      Dariusz Wyrzykowski, Iwona Inkielewicz-Stępniak, Justyna Czupryniak, Dagmara Jacewicz, Tadeusz Ossowski, Michal Woźniak and Lech Chmurzyński

      Version of Record online: 29 MAY 2013 | DOI: 10.1002/zaac.201300152

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    6. Four Complexes with the Rigid Ligand 1,4-Bis(1H-imidazol-4-yl)benzene and Varied Carboxylate Ligands (pages 1808–1814)

      Shui-Sheng Chen, Rui Qiao, Liang-Quan Sheng, Song Yang and Zhao-Di Liu

      Version of Record online: 12 JUN 2013 | DOI: 10.1002/zaac.201300189

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    7. Synthesis, Crystal Structures, and Magnetic Properties of Two Tetrahedral MnIIMnIII3 Complexes (pages 1821–1826)

      Pei-Pei Yang, Li-Li Zhu, Yun Xu and Cong-Ying Shao

      Version of Record online: 12 JUN 2013 | DOI: 10.1002/zaac.201300149

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    8. 3Mg(OH)2·MgSO4·8H2O: A Metastable Phase in the System Mg(OH)2-MgSO4-H2O (pages 1827–1833)

      Robert E. Dinnebier, Melanie Pannach and Daniela Freyer

      Version of Record online: 7 JUN 2013 | DOI: 10.1002/zaac.201300128

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    9. Vapor Composition over Solid Indium Trichloride and in ­Indium Chloride Unsaturated Vapor (pages 1840–1844)

      Viacheslav I. Tsirelnikov, Petr Melnikov and Valter A. Nascimento

      Version of Record online: 12 JUN 2013 | DOI: 10.1002/zaac.201300186

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    10. Synthesis, Structures, and Properties of Two Novel Coordination Polymers with a V-shaped Diphosphonate Ligand (pages 1845–1849)

      Xiaoxia Lv, Sifu Tang, Liangjun Li, Xianrui Xu and Xuebo Zhao

      Version of Record online: 12 JUN 2013 | DOI: 10.1002/zaac.201300185

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    11. Crystal Structures and Luminescent Properties of Two Zinc(II) Coordination Compounds with a β-Diketonate Derivative Ligand (pages 1850–1854)

      Hong-Na Zhang, Jin Wang, Huai-Ming Hu, Fei Yuan, Juan Song and Gang-Lin Xue

      Version of Record online: 12 JUN 2013 | DOI: 10.1002/zaac.201300090

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    12. 1-Alkyl-2-{(O-Thioalkyl)Phenylazo}Imidazole Complexes of PbII and Their Photochromic Property (pages 1861–1870)

      Shefali Saha Halder, Suman Roy, Tapan Kumar Mondal, Rajat Saha and Chittaranjan Sinha

      Version of Record online: 19 JUN 2013 | DOI: 10.1002/zaac.201300173

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    13. A DFT Study on Estrone – TNT Interaction (pages 1871–1875)

      Lemi Türker and Çağlar Çelik Bayar

      Version of Record online: 2 JUL 2013 | DOI: 10.1002/zaac.201300239

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    14. Synthesis, Structures and DFT Studies of Imido-bridged and (Bis)ligand-coordinated Titanium Complexes (pages 1876–1883)

      Jian Wu, Yanmei Chen, Zhou Chen, Wei Liu, Yahong Li, Hao Pei, Yonglu Liu, Qian Gao and Wu Li

      Version of Record online: 17 JUN 2013 | DOI: 10.1002/zaac.201300100

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    15. Synthesis, Structures, and Luminescent Properties of two 3, 5-Dimethyl-1-H-1, 2,4-triazole-Based Zinc Metal-Organic Frameworks with Aromatic Carboxylate as Coligand (pages 1884–1887)

      Yao Huang, Long-Jiang Liu, Ming-Shan Zhou, Xiao-Jun Zhou, Chao Zhu, Fei-E Fu and Yong-Ming Zhang

      Version of Record online: 13 JUN 2013 | DOI: 10.1002/zaac.201300068

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    1. Top of page
    2. Cover Picture
    3. Contents
    4. Review
    5. Short Communications
    6. Articles
    7. Preview

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