Zeitschrift für anorganische und allgemeine Chemie

Cover image for Vol. 639 Issue 14

Special Issue: Contributions dedicated to Professor Bernt Krebs on the Occasion of His 75th Birthday

November 2013

Volume 639, Issue 14

Pages 2361–2667

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      Cover Picture: ZAAC - Journal of Inorganic and General Chemistry 14/2013 (page 2361)

      Article first published online: 5 NOV 2013 | DOI: 10.1002/zaac.201390032

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      The cover picture shows the cationic cluster [Ru(Bi8)2]6+, which is part of the metal-rich bromide Bi39.67(7)Ru2Br35.0(2). The isolated Bi82+ polycation was first described by Bernt Krebs in 1982. Here two of them coordinate a ruthenium(II) cation. The η4-coordination can be regarded as a multi-center bonding, in which a combination of Bi-6p orbitals provides intra-ligand Bi?Bi bonding and simultaneously acts as a donor towards the transition metal atom. A transfer of six electrons per polycation and thus an 18-electron situation for the central atom can be inferred. More details are discussed in the article by Ruck et al. on pp. 2401ff.

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    1. Copper Substitution and Mixed Cation Effect in Ag10Te4Br3 (pages 2379–2381)

      Malte Giller, Melanie Bawohl, Alexandra P. Gerstle and Tom Nilges

      Article first published online: 22 JUL 2013 | DOI: 10.1002/zaac.201300309

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    2. The Reducing Ability of Cycloheptatrienyl-Cyclopentadienyl Zirconium Sandwich Complexes towards Silver(I) (pages 2386–2389)

      Alain C. Tagne Kuate, Lukas Pinkert, Matthias Freytag, Peter G. Jones and Matthias Tamm

      Article first published online: 15 OCT 2013 | DOI: 10.1002/zaac.201300441

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    3. Lithium-cyclopropylethinylamidinates (pages 2390–2394)

      Farid M. A. Sroor, Cristian G. Hrib, Liane Hilfert and Frank T. Edelmann

      Article first published online: 8 OCT 2013 | DOI: 10.1002/zaac.201300424

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    1. Shape-stabilized Bi2Te3-capped Tellurium Nanorods (pages 2406–2410)

      Hailong Dong, Radian Popescu, Dagmar Gerthsen and Claus Feldmann

      Article first published online: 25 OCT 2013 | DOI: 10.1002/zaac.201300536

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    2. Synthesis, Crystal Structure, and Properties of the Ordered Double Perovskite Sr2CoOsO6 (pages 2421–2425)

      Avijit Kumar Paul, Manfred Reehuis, Claudia Felser, Paula M. Abdala and Martin Jansen

      Article first published online: 20 SEP 2013 | DOI: 10.1002/zaac.201300429

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    3. Zn3 and Ga3 Triangles as Building Units in Sr2Au6Zn3 and Sr2Au6Ga3 (pages 2444–2449)

      Birgit Gerke, Rolf-Dieter Hoffmann and Rainer Pöttgen

      Article first published online: 6 SEP 2013 | DOI: 10.1002/zaac.201300366

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    4. Reaction of Unsaturated Vicinal Phosphane/Borane Frustrated Lewis Pairs with Benzaldehyde (pages 2455–2462)

      Olga Ekkert, Gerald Kehr, Constantin G. Daniliuc, Roland Fröhlich, Birgit Wibbeling, Jeffrey L. Petersen and Gerhard Erker

      Article first published online: 18 OCT 2013 | DOI: 10.1002/zaac.201300421

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    5. The First Phosphates of Heptavalent Rhenium (pages 2463–2472)

      Saiful M. Islam, Robert Glaum, Axel Pelka, Jörg Daniels and Wilfried Hoffbauer

      Article first published online: 16 AUG 2013 | DOI: 10.1002/zaac.201300289

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    6. Synthesis and Crystal Structure of (1,3-Diammoniumpropane)3[V4W9O40]·H2O (pages 2482–2486)

      Michael Hinz, Christian Näther and Wolfgang Bensch

      Article first published online: 25 OCT 2013 | DOI: 10.1002/zaac.201300423

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    7. Snapshots of the Formation of NaTi3O6(OH)·2H2O Nanowires: A Time-Resolved XRD/HRTEM Study (pages 2521–2526)

      Dominik Koll, Iryna Andrusenko, Enrico Mugnaioli, Alexander Birkel, Martin Panthöfer, Ute Kolb and Wolfgang Tremel

      Article first published online: 22 OCT 2013 | DOI: 10.1002/zaac.201300411

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    8. Hexacarbonyl (Trimethylsilyl Ethyne) Dicobalt as MOCVD Precursor for Thin Cobalt Layer Formation (pages 2532–2535)

      Colin Georgi, Alexander Hildebrandt, André Tuchscherer, Steffen Oswald and Heinrich Lang

      Article first published online: 15 AUG 2013 | DOI: 10.1002/zaac.201300292

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    9. Disorder and Transport Properties of In3SbTe2 – an X-ray, Neutron and Electron Diffraction Study (pages 2536–2541)

      Thorsten Schröder, Tobias Rosenthal, Sebastian Grott, Christian Stiewe, Johannes de Boor and Oliver Oeckler

      Article first published online: 15 AUG 2013 | DOI: 10.1002/zaac.201300317

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    1. The Lithium Fluoride Tetrafluoroborate Li2F[BF4] (pages 2555–2557)

      Thomas Pilz, Thomas Schleid and Martin Jansen

      Article first published online: 29 OCT 2013 | DOI: 10.1002/zaac.201300525

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    2. K[Al4(PPh2)7PPh]: An AlII Phosphanide / Phosphinidene Intermediate on the Path to AlP Formation (pages 2558–2560)

      Dennis H. Mayo, Yang Peng, Samantha DeCarlo, Xiang Li, James Lightstone, Peter Zavalij, Kit Bowen, Hansgeorg Schnöckel and Bryan Eichhorn

      Article first published online: 30 OCT 2013 | DOI: 10.1002/zaac.201300359

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    3. RuCl2(PPh3)2(N-ppa) – A Hydrogen-Bridged Ruthenium(II) Complex of N-Pyrazolylpropanamide (pages 2561–2564)

      Cristian G. Hrib, Frank T. Edelmann, Charles W. Smith IV, Kent C. McQueen, Santina S. Cruz, Donna S. Amenta and John W. Gilje

      Article first published online: 6 SEP 2013 | DOI: 10.1002/zaac.201300227

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    1. Infinite Linear Zinc Chains in AAu4Zn2 (A = Ca, Ce, Pr, Nd) with YbAl4Mo2 Type Structure (pages 2575–2580)

      Birgit Gerke, Oliver Niehaus, Rolf-Dieter Hoffmann and Rainer Pöttgen

      Article first published online: 4 JUL 2013 | DOI: 10.1002/zaac.201300260

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    1. Synthesis and Molecular Structure of [Fe2(μ-PtBu2)2(NO)4] (pages 2609–2611)

      Hans-Christian Böttcher, Peter Mayer and Tobias Mayer

      Article first published online: 20 SEP 2013 | DOI: 10.1002/zaac.201300346

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    1. Synthesis and Structural Characterization of Compounds Containing the Al–O–Al Motif (pages 2618–2622)

      Zhi Yang, Pengfei Hao, Zhihong Liu, Xiaoli Ma, Herbert W. Roesky, Ying Yang and Jiarong Li

      Article first published online: 13 SEP 2013 | DOI: 10.1002/zaac.201300386

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    2. New Rhodium-rich Germanides RERh6Ge4 (RE = Y, La, Pr, Nd, Sm–Lu) (pages 2623–2630)

      Daniel Voßwinkel, Oliver Niehaus and Rainer Pöttgen

      Article first published online: 20 SEP 2013 | DOI: 10.1002/zaac.201300369

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    4. Tungsten Oxychloride Compounds Containing [W6O6Cl12]n– (n = 2, 3) Clusters (pages 2637–2642)

      Thorsten Hummel, Jochen Glaser, Markus Ströbele and H.-Jürgen Meyer

      Article first published online: 9 SEP 2013 | DOI: 10.1002/zaac.201300326

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    5. Phase Chemistry in the Ca-Mn-Sb-O System at 1160–1250 °C (pages 2657–2663)

      Gennady V. Bazuev, Aleksander P. Tyutyunnik and Boris G. Golovkin

      Article first published online: 13 SEP 2013 | DOI: 10.1002/zaac.201300269

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