Helium isotopes are a robust geochemical tracer of a primordial mantle component in hot spot volcanism. The high 3He/4He (up to 35 RA, where RA is the atmospheric 3He/4He ratio of 1.39 × 10−6) of some Hawaiian Island volcanism is perhaps the classic example. New results for picrites and basalts from the Hawaiian-Emperor seamount chain indicate that the hot spot has produced high 3He/4He lavas for at least the last 76 million years. Picrites erupted at 76 Ma have 3He/4He (10–14 RA), which is at the lower end of the range for the Hawaiian Islands but still above the range of modern mid-ocean ridge basalt (MORB; 6–10 RA). This was at a time when hot spot volcanism was occurring on thin lithosphere close to a spreading ridge and producing lava compositions otherwise nearly indistinguishable from MORB. After the hot spot and spreading center diverged during the Late Cretaceous, the hot spot produced lavas with significantly higher 3He/4He (up to 24 RA). Although 3He/4He ratios stabilized at relatively high values by 65 Ma, other chemical characteristics such as La/Yb and 87Sr/86Sr did not reach and stabilize at Hawaiian-Island-like values until ∼45 Ma. Our limited 3He/4He record for the Hawaiian hot spot shows a poor correlation with plume flux estimates (calculated from bathymetry and residual gravity anomalies [Van Ark and Lin, 2004]). If 3He is a proxy for the quantity of primordial mantle material within the plume, then the lack of correlation between 3He/4He and calculated plume flux suggests that variation in primordial mantle flux is not the primary factor controlling total plume flux.