The Cape Verde Frontal Zone separates North and South Atlantic Central Waters in the eastern North Atlantic Subtropical Gyre. CTD-O2 and shipboard ADCP data from three hydrographic sections carried out in September 2003 are used to study the structure of the front. Results show the relation between spatial variations of water masses and currents, demonstrating the importance of advection in the distribution of water masses. Diapycnal diffusivities due to double diffusion and vertical shear instabilities are also estimated. Existence of competition between the two processes through the water column is shown. Depth-averaged diffusivities suggest that salt fingering dominates diapycnal mixing, except areas of purest South Atlantic Central Water. Here, double diffusion processes are weak and, consequently, shear of the flow is the main process. Results also show that strong mixing induced by vertical shear is associated with a large intrusion found near the front.
 The thermocline waters of the North Atlantic Subtropical Gyre flow southward to latitudes near Cape Blanc, where they turn west away from the coast. The southward flow is commonly identified with the Canary Current, while the westward turn is the beginning of the North Equatorial Current flowing north of the Cape Verde Frontal Zone (CVFZ). This term was introduced by Zenk et al.  to characterize the eastern part of the Central Water Boundary, which is the transition zone between North Atlantic Central Water (NACW) and South Atlantic Central Water (SACW). In the past, several surveys have taken place at the CVFZ to study the distribution and variability of water masses and its relation with the upwelling off West Africa [Hughes and Barton, 1974; Manriquez and Fraga, 1982; Barton, 1987; Zenk et al., 1991]. The CVFZ is described as a strong meandering thermohaline front near Cape Blanc at latitudes close to 20°N. It shows sharp gradients in temperature and salinity in the upper 600 m and the presence of intrusions, produced by interleaving of NACW and SACW across the front with typical vertical scales of 10–100 m.
 One important aspect of the CVFZ is the compensating character of the temperature and salinity fields, which cause horizontal density gradients to be relatively small across the front. This peculiarity is an important factor in reducing the vertical shear of the horizontal velocity in some parts of the frontal region. Klein and Tomczak  and Klein and Siedler  have used multiparameter analysis to analyze diapycnal mixing at the CVFZ. They found significant diapycnal fluxes in the Central Water layers, with water mass composition being changed by more than 20% through diapycnal mixing. The nearly density compensated character of the front and the density ratio results, let them to suggest that double diffusion is the main cause of the observed diapycnal mixing. They conclude that double-diffusive salt flux is an important process for the salt balance in this water mass, and is balanced either by isopycnal advection or isopycnal eddy diffusion.
 However, the role of mixing induced by vertical shear of the current in the CVFZ has not been quantified yet. The main purpose of our study is to estimate the relative importance of vertical shear and double diffusion processes in the diapycnal mixing in different parts of the frontal zone.
2. Data and Methods
 The data presented here consist of 39 SeaBird 911+ CTD (Conductivity, Temperature, Depth) stations taken along three sections in the CVFZ between 20° and 26°N and between 18° and 26°W (Figure 1). Measurements were taken during the CORICA oceanographic survey carried out aboard the R/V Thalassa in September 2003. CTD-O2 data from the western and southern sections have been already used to investigate the spatial variability of the Canary Current, by means of an inverse box model by Hernández-Guerra et al. . In this paper we concentrate on the upper 600 m of the three sections, adding the analysis of the shipboard ADCP (Acoustic Doppler Current Profiler) velocity data recorded during the cruise. Distance intervals between stations were approximately 0.4°, except for the African slope stations which were 0.1° apart and the eastern section where the stations had a spacing of 1°. Water samples were collected at each station for the CTD sensor calibration and the analysis of dissolved oxygen. The shipboard ADCP (a narrowband 75-kHz frequency) provided mean current profiles relative to the ship every 5 min in 16-meter bin lengths. Data were required to pass a test of the return signal (Percent Good >90%), acceptable second derivatives of horizontal and vertical velocity components with respect to depth, and reasonable error velocities as recommended by Firing et al. . The ADCP data shallower than 600-m depth usually satisfied these criteria. The velocities were calibrated for transducer misalignment and adjusted from ship relative currents to absolute currents using GPS position measurements.
 The density ratio, Rρ, is the parameter that dictates a system's susceptibility to double-diffusive instability [Thorpe, 2005]. Density ratios were calculated from CTD data using central differences over the same depth intervals as the ADCP data. With these Rρ we were able to estimate double diffusion diapycnal diffusivities, Kd, using the Schmitt  parameterization for the salt-finger type, and the Kelley  parameterization for the diffusive type. With potential densities and vertical shear from CTD and ADCP measurements respectively, buoyancy frequencies and gradient Richardson numbers (Ri) were calculated. Finally, the vertical shear stress diffusivities, Ks, have been estimated using the Pacanowski and Philander  parameterization and the Ri values. A full description of the method can be found in the work of Rodríguez-Santana et al. . The scales of the instabilities induced by vertical shear are on the order of 1–10 m [Pelegrí and Sangrá, 1998] implying that the depth interval used in the calculation of Ri, should be greater than these values. The use of relatively large vertical intervals produces a smoothing effect on Ri, and consequently on Ks, that has been analyzed by Miller and Evans . Nevertheless, in this work, the Kd values have been calculated with the same averaging depth intervals (16 m) as for Ks, allowing a comparison between them to be made.
3. Results and Conclusions
3.1. Structure of the Front
 An accepted criterion for the position of the CVFZ is the location of the 36.0 isohaline at 150 m depth [Barton, 1987; Zenk et al., 1991]. At the southern section, this criterion puts the front at station 64 (21°W) (Figure 2). This figure suggests that the CVFZ approaches the southern section at station 66 (20.5°W). A common characteristic observed in the vertical sections of temperature, salinity and dissolved oxygen is the fluctuation of the isolines, forming consecutive domings. The fluctuations appear to be related to the meandering of the front and the probable presence of eddies. We find upward domings around 24°W, 21°W and 18°–19°W, which are related to the penetration of SACW to the north. The 21°W doming, located at station 65, forms a core of minimum salinity (∼35.6) between 100–300 m depth that coincides with a core of minimum oxygen (<60 μmole kg−1), indicating the presence of a northward entrainment of SACW. A clear relation between domings and currents is observed near the front. The upward domings are found, approximately, in zones with northward currents, while downward domings are situated where currents flow to the south. These results suggest that water mass distribution is correlated with mesoscale activity at the CVFZ, illustrating the importance of horizontal advection.
 The second column of Figure 2 shows the results for the eastern section. This section also shows mesoscale variability with alternating westward and eastward flowing currents. However, the currents reveal essentially a net westward flow along the section that is coherent with the presence of the southwest extension of the Canary Current north of the CVFZ. The front is found between stations 77 (21°N) and 78 (22°N). The results show a meander or eddy structure that produces a SACW penetration centred at station 77. Oxygen values <60 and 100 μmole kg−1 are observed again in the purest SACW, and at the front position, respectively. The position of the front coincides with a change of velocity direction: station 77 (21°N) shows a northwestward current that is advecting the tongue of SACW. At the western section (not shown), the 36.0 isoline does not reach 150 meters depth, indicating that the section does not cross the CVFZ. However, the salinity, temperature and oxygen values at station 55 reveal the nearness of the front at the southern extreme of this section. The current vectors of Figure 1 evidence a mean westward flow along this section as well as in the eastern section.
3.2. Diapycnal Mixing
Figure 3 shows depth averaged values and standard deviations of the diffusivities obtained for the 150–600 m depth layer (approximately the Central Water layer). The results show that Ks are of the order of 10−5 ± 10−6 m2 s−1 and vary little along the sections, except at station 65 where we obtain the highest mean value and standard deviation (∼3×10−5 ± 4.5 × 10−5 m2 s−1). The mean values of Kd suggest that double diffusion dominates the diapycnal mixing in the studied region, except where purer SACW is found (i.e. the eastern border of the southern section). Here, the diffusivity coefficients due to double diffusion are clearly small (<10−5 m2 s−1) and, consequently, diapycnal mixing induced by the vertical shear of the flow is the dominant process. The standard deviations of Kd show a tendency to increase toward the front, indicating that in the frontal area both processes compete through mixing in the water column.
Figure 4 shows potential temperature-salinity (θ-S) diagrams and vertical distributions of different variables at six stations. Station 43 is far from the front and shows typical NACW salinity and temperature values. Station 72 shows SACW properties, and the remaining stations have intermediate values, indicating a mixture of the two water masses. An inspection of the results shows that the complex variation of currents in the vertical direction governs most of the distribution of water masses at the places situated close the front (stations 62, 65, 77). This can be seen especially at station 65, where the cores of minimum salinity and minimum oxygen (mentioned in the previous section) are in fact caused by a large intrusion of highly saline NACW that flows to the south at 300 m depth between northward-flowing SACW layers.
 Since the dependence of the strength of double diffusive mixing on Rρ is complex, the Turner angle, Tu, [Ruddick, 1983] is used in Figure 4 instead of Rρ. Turner angles between −90 and −45° indicate that that portion of the profile is unstable to diffusive layering, whereas Turner angles up to 45° indicate that the portion of the profile is unstable to salt fingering, with the strongest activity near 90°. The Turner angles for the selected stations are shown in the third column of Figure 4. The regime of nearly constant Tu over the depth range 150–600 m in the region of undisturbed NACW (station 43) is in contrast with the situation in the frontal zone. Here, the vertical profiles of Tu show a high variability and the presence of diffusive layering regions generated by intrusions. The results for Tu also illustrate that salt fingering in NACW is stronger than in SACW. In the SACW the values for Kd (Figure 4, sixth column) decrease strongly, especially between 200 and 400 m depth, where the salt-fingering decrease due to the lower vertical gradients of salinity and temperature. This result is probably a consequence of enhanced mixing in the SACW during its journey through the equatorial current system.
 Within a thermohaline front, the boundary area between two water masses increases through the occurrence of intrusions. These features, which are visible as large fluctuations or inversions in the profiles, are thought to enhance double diffusive diapycnal mixing [Barton, 1987; Klein and Siedler, 1995]. The calculated diffusivity coefficients shown in Figure 4 indicate that the presence of intrusions at the front increases the fluctuation of the diapycnal mixing due to double diffusion along the water column. This effect is due to the generation of layers of enhanced double diffusion: salt fingering under warm, salty intrusions and diffusive convection above; diffusive convection under cold, fresh intrusions and salt fingering above. Between these two layer types, layers of diffusive stability appear that produce the minima of Kd. The results also show that large intrusions can generate important enough velocity gradients to produce gradient Richardson numbers less than one, implying strong mixing. Station 65 shows such behaviour, where maximum values of Ks of about 2 × 10−4 m2 s−1 are obtained. Therefore, large intrusions, often observed in the past at the CVFZ, may favour diapycnal mixing induced by vertical shear in the water column to the detriment of double diffusion. The obtained results in this study suggest that estimations of diapycnal mixing in the CVFZ should include instabilities due to vertical shear, as well as double diffusive processes.
 This work has been supported by the Spanish Ministerio de Educación y Ciencia under the CORICA project (REN2001-2649-C02-01).